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Theoretical study of the variations in the β-protons hyperfine splitting parameter of hydrocarbon radicals

✍ Scribed by Marina Brustolon; Carlo Corvaja; Giovanni Giacometti

Book ID
104791589
Publisher
Springer
Year
1971
Tongue
English
Weight
644 KB
Volume
22
Category
Article
ISSN
1432-2234

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📜 SIMILAR VOLUMES

Angular dependence of the β-proton hyper
Angular dependence of the β-proton hyperfine coupling constant in β-substituted ethyl radicals
✍ Maurizio Guerra 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 584 KB

The p-proton hypertine coupling constants in S-substituted ethyl radicals CH2-CH2-X (X=CHJ, NH2, OH, F, SiH9, PH2, SH, Cl) were computed as a function of the rotational angle (Y about the C.C, bond by ab initio calculations at the UHF/DZ+d level. They follow the relation aHg (0,a) =A+ B cos\*O + Cco