Theoretical study of the structure and vibrational spectrum of 1,3-dithiole-2-thione
β Scribed by Ruifeng Liu; Alex S. VanBuren; Paula R. Moody; Joel A. Krauser; Dennis R. Tate; Jeffrey A. Clark
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 538 KB
- Volume
- 52
- Category
- Article
- ISSN
- 1386-1425
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A novel D3T derivative, 5-amino-4-cyano-3H-1,2-dithiole-3-thione (compound 1) has been obtained in one-pot reaction. The crystal is orthorhombic, space group Pbca, with a = 10.3667(4) A Λ, b = 10.8898(4) A Λ, c = 11.4942(5) A Λ, V = 1297.60(9) A Λ3, and Z = 8. In the crystal, molecules are firstly s
The electron impact ionization mass spectra of 4,5-bis(alkylthio)-l,3dithiole-2-thiones and their 1,'tdithiole-3thione isomers were studied by accurate mass measurements and linked scans. The relative abundance of ions formed following the extrusion of S, , CS or CS, allows an unambiguous isomer dif