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Theoretical study of the structure and NMR properties of μ-hydrido-bridged carbocations and carbodications

✍ Scribed by V Galasso


Book ID
108430782
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
142 KB
Volume
241
Category
Article
ISSN
0301-0104

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📜 SIMILAR VOLUMES


Theoretical study of structure and NMR p
✍ V. Galasso 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB 👁 1 views

Full conformational analysis on the cyclodecyl cation was performed at the HFr6-31G\*\* level of theory. The most stable conformer is established as having a boat᎐chair structure with a 1,5-transannular interaction and a symmetrical and bent -hydrido bridge, which involves a two-electron three-cente

A theoretical study of the structure and
✍ J.R. Sabin; H. Kim 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 500 KB

An nb initio LCCO Al0 SCI? olcuhtion with a full geometry srarch is urried out on CC)>. The structure is dctermined to have Czv symmetry with C-O hot??. bngths of 1.265 .A and 1 A73 A and a bond angk of 66.X". The unique oxygen atom is apparently of the cubouyl type and there is a weak bond between