Theoretical study of the reaction H+D2→HD+D. Possible tunneling processes for high energies (Etr > 2 eV)
✍ Scribed by Michael Baer
- Book ID
- 103665472
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 630 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0301-0104
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📜 SIMILAR VOLUMES
The reaction H+Da+HD( u'= 1, j') t D was studied using two different experimental geometries: (1) a probe-laser-induced reaction geometry and (2) an independent-photolysis laser geometry. High-energy H atoms were generated by photolysis of HI which resulted in center-of-mass collision energies of 2.
Complete quantum state distributions for HD (u= 1) and HD(u=2) are obtained by photolyzing HI at 266 nm m the presence of D2 and detecting the nascent HD product via (2+ 1) resonance-enhanced multiphoton ionization (REMPI). Calibration against an effusive oven source ( d 1800 K) yields any necessary
The reaction D+ H2( v= I ) has been investigated in a crossed molecular beam experiment at the most probable collision energy of&=0.33 eV. Angular and time-of-flight distributions have been measured and the total absolute cross section has been determined to be a&, = 0, v= 1, EC ,,,. = 0.33 eV) = 1.