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Theoretical Study of the Low-Barrier Hydrogen Bond in the Hydrogen Maleate Anion in the Gas Phase. Comparison with Normal Hydrogen Bonds

✍ Scribed by Garcia-Viloca, Mireia; González-Lafont, Angels; Lluch, José M.

Book ID
127185220
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
243 KB
Volume
119
Category
Article
ISSN
0002-7863

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There are large differences between the acidity of the enol of the acyclic diketone, 2,4-pentanedione and those of two cyclic diketones, 1,3-cyclopentanedione and 1,3-cyclohexanedione. Computational studies have demonstrated that these differences are largely due to the strength of the internal low-