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Theoretical study of the interaction between Au(I) and I on the [AuI2]−–I2 complexes

✍ Scribed by Fernando Mendizabal


Book ID
108286099
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
247 KB
Volume
955
Category
Article
ISSN
0166-1280

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✍ N. V. Gorbunova; A. P. Purmal; Yu. I. Skurlatov; S. O. Travin 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 992 KB

The mechanism of the interaction of Cu+-a,a'-dipyridyl complex (Cu+Lz) with 0 2 in both neutral and acid media was studied by the stopped-flow method. The dependence of the mechanism on the acidity of the medium was established. In an acid medium H+ participated in a direct 0 2 reduction to HOn by i