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Theoretical Study of the Insertion Reactions of Aluminum with H 2 O, NH 3 , HCl, and Cl 2

✍ Scribed by Fängström, Torbjörn; Lunell, Sten; Kasai, Paul H.; Eriksson, Leif A.


Book ID
125902786
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
178 KB
Volume
102
Category
Article
ISSN
1089-5639

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Theoretical study on the insertion react
✍ Chaojie Wang; Song Ye 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 1 views

The insertion reactions of the titanium atom cation Ti F into HF, HCl, H O, H S, NH , PH , CH , and SiH have been studied by ab initio molecular orbital 2 2 3 3 4 4 theory. All these reactions involve the initial formation of an intermediate complex followed by a hydrogen migration process via a tr