𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Theoretical study of the hydrogen abstraction by chlorine atoms for CH2BrCl and CHBrCl2

✍ Scribed by Xiao, Jing-Fa; Li, Ze-Sheng; Ding, Yi-Hong; Liu, Jing-Yao; Huang, Xu-Ri; Sun, Chia-Chung


Book ID
121184548
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
171 KB
Volume
4
Category
Article
ISSN
1463-9076

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Kinetic isotope effect for hydrogen/deut
✍ Yannis G. Lazarou; Panos Papagiannakopoulos πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 462 KB

The kinetic isotope effect for the abstraction of hydrogenideuterium from dimethylnitramine and dimethylnitramine-ds by chlorine atoms has been studied in the temperature range 273-353 K. The rate constant ratio k H / k D is given by the Arrhenius expression, k H / k o = (0.92 t-0.07)exp(286 ? 250/R

Rate constants and kinetic isotope effec
✍ E. Tschuikow-Roux; F. Faraji; Jan Niedzielski πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 804 KB

The abstraction of hydrogen and deuterium from 1,2-dichIoroethane, 1,1,2trichloroethane, and two of their deuterated analogs by photochemically generated ground state chlorine atoms has been investigated in the temperature range 0-95Β°C using methane as a competitor. Rate constants and their temperat

Kinetic mechanism of the hydrogen abstra
✍ Yue-meng Ji; Xiao-lei Zhao; Ze-sheng Li; Jing-yao Liu πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 396 KB πŸ‘ 2 views

## Abstract The mechanisms of the reactions: CH~3~CFCl~2~ + Cl (R1) and CH~3~CF~2~Cl + Cl (R2) are studied over a wide temperature range (200–3000 K) using the dual‐level direct dynamics method. The minimum energy path calculation is carried out at the MP2/6‐311G(d,p) and B3LYP/6‐311G(d,p) levels,