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Theoretical Study of the Electronic States of the Rb2 Molecule

✍ Scribed by Su Jin Park; Sung Won Suh; Yoon Sup Lee; Gwang-Hi Jeung

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
156 KB
Volume
207
Category
Article
ISSN
0022-2852

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✦ Synopsis

We have calculated the electronic states of Rb 2 by multireference configuration interactions using the averaged relativistic effective small-core potential and the core-polarization potential. The potential energy curves for a large number of states dissociating into from 5s + 5s up to 7s + 5s asymptotic limits are calculated and the spectroscopic constants are reported. The spin-orbit effects for the states dissociating into 5p + 5s and 4d + 5s are calculated using the effective spin-orbit potential. The results are compared with available experimental data and other theoretical works.

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