Theoretical study of the derivative hydrocarbons of biphenylene. I. Electronic spectrum of the biphenylene
✍ Scribed by F. Peradejordi; R. Domingo; J. I. Ferńndez-Alonso
- Book ID
- 104577639
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 744 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0020-7608
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The two-photon spectra of biphenylene (BP) and 2,3,6,7-tetra-ethyl-biphenylene (TEBP) have been measured in the region of the lowest two electronic transitions (310-440 nm). The S, -+ S, transition of BP, although group-theoretically allowed, is only weakly observed. The TEBP spectrum is, for both t
The vibronic sequences shown by the SI+So spectrum of biphenylene have been calculated by means of the relevant vibronic coupling and Franck-Condon factors. The results of our calculations make it possible to identify the bzu modes and a, modes responsible for the spectrum and involved in the radiat