Ab initio SCF and MP2 calculations have been performed on the structural and energetic properties of HsO-2C0. Three possible energy minima were found, all forming almost linear hydrogen bonds. The most stable species was observed when both carbon monoxide monomers were attached to water via the carb
β¦ LIBER β¦
Theoretical study of the dependence of structural parameters of the H bond in the complex NH3H2CO2H+on position of the proton
β Scribed by R. M. Minyaev; G. V. Orlov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1988
- Tongue
- English
- Weight
- 319 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-4766
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Electron pulse radiolysis a t -298'K of 2 atm Hz containing 5 torr 0 2 produces HOz free radical whose disappearance by reaction (I), HOz + HOz -HzOz + 0 2 , is monitored by kinetic spectrophotometry a t 230.5 nm. Using a literature value for the HOz absorption cross section, the values k = 2.5 X cm