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Theoretical Study of the Conversion of Sulfonyl Precursors into Chains of Poly( p -phenylene vinylene)

✍ Scribed by Claes, L.; François, J.-P.; Deleuze, M. S.


Book ID
126917464
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
112 KB
Volume
125
Category
Article
ISSN
0002-7863

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The thermal conversion of the tetrahydro
✍ M. Herold; J. Gmeiner; M. Schwoerer 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 337 KB 👁 2 views

This paper reports the thermal conversion of the tetrahydrothiophene (THT)-precursor to poly(p-phenylene vinylene) (PPV). Detailed investigations of the conversion process show that the leaving groups THT and HCl do not eliminate simultaneously. Moderate temperatures ( 125 °C) are sufficient to elim