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Theoretical study of the (3sσ)1Π Rydberg state of CO

✍ Scribed by David L. Cooper; Kate Kirby

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
306 KB
Volume
152
Category
Article
ISSN
0009-2614

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✦ Synopsis

A Rydberg state of CO, the first in a series converging to the A 'n excited state of CO+, has been characterized by ab initio configuration interaction calculations. This state, which we denote (3so)'fI. is the inner well of our third adiabatic state of 'Fl symmetry and lies at a 7;. value of 12.76 eV. A vibrational analysis has been carried out and the dipole transition moment with the X 'Z+ ground state has been obtained. We find that absorption oscillator strengths for (3so)'n( v' )tX 'C* (t"' =0) transltions are fairly large, i.e. z I X lo-'.

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✍ Takashi Masaki; Yukio Adachi; Chiaki Hirose 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 297 KB

The inter-Rydberg 4po K 'Z +-3so B 'X + and 4px L 'II-3~0 B 'Z + transitions of CO have been newly observed at 16 134 and 16357 cm -I, respectively, by optogalvanic spectroscopy of the hollow cathode discharge of He/CO mixture gas.