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Theoretical Study of Raman Spectra of Methanol in Aqueous Solutions: Non-Coincident Effect of the CO Stretch

✍ Scribed by Sun, Yuanyuan; Zheng, Renhui; Shi, Qiang

Book ID
115496877
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
453 KB
Volume
116
Category
Article
ISSN
0022-3654

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The Raman non-coincidence e †ect (NCE) of the carbonyl stretching band of methyl formate diluted in acetonitrile was studied. The observed NCE was compared with the predictions of a number of models for non-isotopic dilutions. All of the models failed. Thermodynamic data indicate that the mixtures a