𝔖 Bobbio Scriptorium
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Theoretical study of PO and PO−

✍ Scribed by Ludwik Adamowicz; Rodney J. Bartlett; Józef S. Kwiatkowski; Willis B. Person

Book ID
104792000
Publisher
Springer
Year
1988
Tongue
English
Weight
464 KB
Volume
73
Category
Article
ISSN
1432-2234

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Contributions of the PO ester and CO tor
Contributions of the PO ester and CO torsion angles of the phosphate group to 31P-nuclear magnetic shielding constant in nucleic acids: Theoretical and experimental study of model compounds
✍ Claude Giessner-Prettre; Bernard Pullman; Fernando Ribas Parado; Doris M. Cheng; 📂 Article 📅 1984 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 685 KB

The magnetic shielding constant of the nucleus of the dimethylphosphate anion is calculated by an eb initio method for different values of the torsion angles about the PO ester bond and different orientations of the methyl groups. The results obtained tend to show that both types of conformational p