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Theoretical study of influence of structure of carbamates on their thermal stability

✍ Scribed by I. B. Dorofeeva; O. G. Tarakanov

Publisher
SP MAIK Nauka/Interperiodica
Year
1987
Tongue
English
Weight
464 KB
Volume
27
Category
Article
ISSN
0022-4766

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πŸ“œ SIMILAR VOLUMES

Theoretical studies on the acid hydrolys
Theoretical studies on the acid hydrolysis of methyl carbamate
✍ Ikchoon Lee; Chang Kon Kim; Byung Choon Lee πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 499 KB

The mechanism of the A2 acid hydrolysis of methyl carbamate was investigated using MNDO method. The reaction was found to proceed in two steps: (1) the rate-determining nucleophilic attack of water on the carbonyl carbon of the N-protonated tautomer involving the tetrahedral TS; and (2) the fast sub