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Theoretical study of Diels-Alder reaction: Role of substituent in regioselectivity and aromaticity

✍ Scribed by A. Mohajeri; M. Shahamirian

Book ID
113009454
Publisher
Iranian Chemical Society
Year
2010
Tongue
English
Weight
447 KB
Volume
7
Category
Article
ISSN
1735-207X

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Silica-supported Lewis acids are good catalysts for Diels-Alder reactions between furan and acrylonitrile and methyl acrylate at room temperature. When 2,5-dimethylfuran is used as the diene, yields of the Diels-Alder adducts with methyl acrylate are lower, due in part to the appearance of aromatiza