Theoretical study of cis-trans isomerization in simple transition-metal complexes
β Scribed by Marynick, Dennis S.; Askari, Sasan; Nickerson, David F.
- Book ID
- 120041270
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 383 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The cis-trans photoisomerization pathway of the s-trans-1,3-pentadiene is investigated on the basis of excited state potential curves calculated using the CIPSI method in the excitonic (PCILO type) scheme. It is shown that both direct and sensitized excitation of either isomer are followed by equipr
The different coordination behavior of the ligand tBuN=Te(Β΅-NtBu)(2)Te=NtBu (L) towards Cu(+) and Ag(+) results from a cis-->trans isomerization. The two Cu(+) ions in [Cu(2)L(3)](2+) (shown schematically) bridge trans and cis isomers of the ligand, whereas the Ag(+) ions in [Ag(2)L(2)](2+) link two