Theoretical study of a nucleophilic addition reaction in the gas phase and in aqueous solution: peptide bond hydrolysis
β Scribed by Ya-Jun Zheng; Rick L. Ornstein
- Book ID
- 114142755
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 681 KB
- Volume
- 429
- Category
- Article
- ISSN
- 0166-1280
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The tautomerism and protonation of 8-azaguanine (azaG) have been studied by means of ab initio methods, both in the gas phase and in aqueous solution. An elimination procedure to choose the most stable tautomeric forms, based on AM1 and HF/6-31G\* energies, has been applied. Tautomers azaG(1,9), aza