Theoretical studies on the potential energy surface and rovibrational states for the electronic ground state of carbonyl sulfide
β Scribed by Daiqian Xie; Yuhui Lu; Dingguo Xu; Guosen Yan
- Book ID
- 108429208
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 293 KB
- Volume
- 270
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
The potential energy surface for the electronic ground state of CO 2 is refined by means of a two-step variational procedure using the exact rovibrational Hamiltonian in the bond length-bond angle coordinates. In the refinement, the observed rovibrational energy levels for J = 0-4 below 16,000 cm -1
We report here an optimization of the parameters in an analytical representation of the potential energy function for the electronic ground state of the water molecule on the basis of experimental data. The calculations are carried out with the MORBID (Morse Oscillator Rigid Bender Internal Dynamics
Using millimeter wave absorption spectroscopy we have recorded pure rotation spectra of MgOH in its ground vibrational state and in six excited vibrational states. We have also determined a large number of bending vibrational energies, and the Mg-O stretching frequency, using dispersed fluorescence