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Theoretical studies on the conformation of saccharides

✍ Scribed by Igor Tvaroška; Tibor Kožár

Book ID
104793258
Publisher
Springer
Year
1986
Tongue
English
Weight
923 KB
Volume
70
Category
Article
ISSN
1432-2234

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📜 SIMILAR VOLUMES

Theoretical studies on the conformation
Theoretical studies on the conformation of saccharides. V. Hydration of the acetal segment in glycosides
✍ Igor Tvaroška; Tibor Kožár 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 648 KB

## Abstract Hydration sites of the acetal segment were studied in five of the most stable conformers of 2‐methoxy‐tetrahydropyran (MTHP) as the first step in the determination of the hydration scheme of glycosides. The intramolecular geometries of a supermolecule formed with MTHP and water were cal

Theoretical studies on the conformation
Theoretical studies on the conformation of saccharides. XIV. Structure and conformational properties of the glycosylamines
✍ Tibor Kožár; Igor Tvaroška 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 586 KB

The 2-methylaminotetrahydropyran was used as a model to study conformational properties of the N-glycosidic linkage in glycosylamines. Relaxed two-dimensional conformational (%, 9 ) maps in 20 solvents were calculated by a method in which the total energy is divided into the energy of the isolated m

Theoretical studies on the conformation
Theoretical studies on the conformation of saccharides. IV. Solvent effect on the stability of β-maltose conformers
✍ Igor Tvaroška 📂 Article 📅 1982 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 613 KB

## Abstract The conformational equilibria of four β‐maltose conformers have been studied theoretically in 12 solvents. The stability of the conformers in dilute solution has been compared by using the continuum reaction field method. The solvation energy consists of electrostatic, dispersion, and c

Theoretical studies on the conformation
Theoretical studies on the conformation of saccharides. VIII. Solvent effect on the stability of β-cellobiose conformers
✍ Igor Tvaroška 📂 Article 📅 1984 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 540 KB

The conformational equilibria of five P-cellobiose conformers have been studied theoretically in 10 solvents. The stability of the conformers in dilute solution has been compared by using the method that has already been tested for X-methoxytetrahydropyran, p-maltose, and Bglucose. The solvation ene