## Abstract Various models proposed for heparin have been examined by a stereochemical approach involving contact distance criteria and potential energy calculations. The present study suggests that the model favored by Atkins and coworkers [__Biochem. J.__ (1973) **135**, 729β733 and (1974) **143*
Theoretical studies on the conformation of aldopyranoses
β Scribed by P.R. Sundararajan; V.S.R. Rao
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 516 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4020
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The 2-methylaminotetrahydropyran was used as a model to study conformational properties of the N-glycosidic linkage in glycosylamines. Relaxed two-dimensional conformational (%, 9 ) maps in 20 solvents were calculated by a method in which the total energy is divided into the energy of the isolated m
## Abstract The conformational equilibria of four Ξ²βmaltose conformers have been studied theoretically in 12 solvents. The stability of the conformers in dilute solution has been compared by using the continuum reaction field method. The solvation energy consists of electrostatic, dispersion, and c