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Theoretical studies on the alkylidene germylenoid H2C=GeLiF and its insertion reaction with R-H (R = F, OH, NH2, CH3)

✍ Scribed by Xiaojun Tan; Weihua Wang; Ping Li; Fei Liu

Book ID: 110184613
Publisher: International Academic Publishing Co (Nauka/Interperiodica)
Year: 2009
Tongue: English
Weight: 216 KB
Volume: 83
Category: Article
ISSN: 0036-0244
DOI: 10.1134/s0036024409080184

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The insertion reactions of the titanium atom cation Ti F into HF, HCl, H O, H S, NH , PH , CH , and SiH have been studied by ab initio molecular orbital 2 2 3 3 4 4 theory. All these reactions involve the initial formation of an intermediate complex followed by a hydrogen migration process via a tr