✍ Scribed by Ernst C. Hass; Paul G. Mezey; Suzanne R. Abrams
No coin nor oath required. For personal study only.
Nonempirical molecular orbital studies on a series of isomeric octyn‐1‐ols indicated that the anomalous stability of the alkoxide of 3‐octyn‐1‐ol isomer is probably related to stereochemical and polarization properties of the molecule. The calculations correlated with the experimental observation that the least stable isomer should be the terminal alkyne, 7‐octyn‐1‐ol.
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The energetics of the urate oxidase reaction has been studied employing HF, MP2, and DFT calculations. Gas-phase energies of possible urate oxidase reaction intermediates were calculated; radical species and dehydrourate had high relative energies while 5-hydroperoxyisourate was stable in the gas ph
Acetylenes are an important and valuable class of compounds in organic synthesis. This book expands on this historically well-established concept, while incorporating the many new developments that have widened the number of applications in this field. It remains the only handbook available that emb
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