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Theoretical studies of the Stevens' rearrangement of alkylammonium ylides

✍ Scribed by George L. Heard; Brian F. Yates


Book ID
114141947
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
537 KB
Volume
310
Category
Article
ISSN
0166-1280

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Mechanism of the Stevens Rearrangement of Ammonium Ylides. -The title rearrangement of the ylide precursor (I) is studied, revealing that the Stevens rearrangement occurs at room temperature. The isomerization to compound (II) is always accompanied by formation of the Sommelet-Hauser rearrangement p

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