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Theoretical studies of the spin-Hamiltonian parameters for the rhombic Mo 5+ tetrahedral centres in ZrSiO 4 crystal from a two-mechanism model

โœ Scribed by Mei, Yang; Zheng, Wen-Chen; Zhang, Lin


Book ID
125845060
Publisher
Taylor and Francis Group
Year
2014
Tongue
English
Weight
133 KB
Volume
112
Category
Article
ISSN
0026-8976

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Theoretical studies of spin-Hamiltonian
โœ Fang Wang; Wu Xiao-Xuan; Zheng Wen-Chen ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 136 KB

In this paper, the high-order perturbation formulas of spin-Hamiltonian (SH) parameters (g factors g J , g ? and zero-field splitting D), including both the crystal-field (CF) and for the first time charge-transfer (CT) mechanisms, are established for 3d 8 ions in trigonal octahedral clusters. By us