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Theoretical Studies of the Reductive C−S Bond Cleavage in Complexes of the Form [M(9S3) 2 ] 2+ (M = Re, Tc, and Ru; 9S3 = 1,4,7-Trithiacyclononane)

✍ Scribed by Maurer, Patrick; Magistrato, Alessandra; Rothlisberger, Ursula


Book ID
126927867
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
262 KB
Volume
108
Category
Article
ISSN
1089-5639

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On reaction of 1,2-bis(2-pyridylmethylthio)-bis-ethylsulphide (L) with copper(II) chloride in presence of an excess of azide ions led to the formation of a new copper(II) complex formulated as [Cu(2-PTrz) 2 (H 2 O) 2 ] (1), where 2-PTrz = 5-(2-pyridyl)-1,3,4-triazole is formed through the cleavage o