Theoretical Studies of Magnetic Interactions in Mn(II)(hfac) 2 {di(4-pyridyl)phenylcarbene} and Cu(II)(hfac) 2 {di(4-pyridyl)phenylcarbene}
β Scribed by Takano, Yu; Kitagawa, Yasutaka; Onishi, Taku; Yoshioka, Yasunori; Yamaguchi, Kizashi; Koga, Noboru; Iwamura, Hiizu
- Book ID
- 118055820
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 378 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4βisobutylβ3,5βdi(2βpyridyl)β4__H__β1,2,4βtriazole (ibdpt) with M(ClO~4~)~2~Β·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~
Cu(II) complexes of 3-[4 0 -dimethylaminophenyl]-1-(2-pyridyl) prop-2-en-1-one (DMAPP) are prepared and characterized by elemental analysis as well as spectral studies (IR and UV-vis), ESR, magnetic susceptibilities and thermal studies. The effect of different alcoholic solvents as well as the tempe