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Theoretical Mechanistic Studies on Oxidation Reactions of Some Saturated and Unsaturated Organic Molecules

✍ Scribed by G. Ghigo; A. Maranzana; M. Causa; G. Tonachini


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxo‐shunt reactions under different experimental conditions wit