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Theoretical investigations on Ziegler-Natta catalysis: models for the cocatalyst components

✍ Scribed by Eini Puhakka; Tuula T. Pakkanen; Tapani A. Pakkanen; Eero Iiskola

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
683 KB
Volume
511
Category
Article
ISSN
0022-328X

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Abstrmct--The model proposed by Cossee for Ziegler-Natta polymerization of propene is re-examined by computing the non-bonded energies for all sets of possible internal coordinates of the atoms at the catalytic site. For catalytic sites in the bulk of ( 110) surfaces of TiCI3-~, it is possible to ex