The spin-Hamiltonian parameters, g factors g J and g ? and hyperfine structure constants 161 A J , 161 A ? , 163 A J and 163 A ? , for Dy 3 + ion at the tetragonal (S 4 ) Ca 2 + site of CaWO 4 crystal are calculated from a diagonalization (of energy matrix) method. In the method, the Zeeman (or magn
โฆ LIBER โฆ
Theoretical investigations on the spin Hamiltonian parameters for Er3+ ion in LiYF4
โ Scribed by Shao-Yi Wu
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 256 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0925-3467
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In this paper, the high-order perturbation formulas of spin-Hamiltonian (SH) parameters (g factors g J , g ? and zero-field splitting D), including both the crystal-field (CF) and for the first time charge-transfer (CT) mechanisms, are established for 3d 8 ions in trigonal octahedral clusters. By us