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Theoretical Investigations on Chalcogen−Chalcogen Interactions: What Makes These Nonbonded Interactions Bonding?

✍ Scribed by Bleiholder, Christian; Werz, Daniel B.; Köppel, Horst; Gleiter, Rolf


Book ID
111644004
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
300 KB
Volume
128
Category
Article
ISSN
0002-7863

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## Abstract In this article, we explored the noncovalent bonding interactions between OCS, SCS, F~2~CS, Cl~2~CS, and singlet carbene. Six chalcogen‐bonded complexes were obtained. It is found that all the vibrational frequencies of CS bond presented a red shift character. Interaction energy,