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Theoretical investigation and experimental detection of rattling motions in atomic and molecular fluids

✍ Scribed by S. Bratos; B. Guillot


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
615 KB
Volume
84
Category
Article
ISSN
0022-2860

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A combined experimental and theoretical study of the homogeneous decomposition of BCl 3 in a H 2 carrier gas is presented. A detailed description of the B/Cl/H thermodynamic equilibrium is first obtained from abinitio calculations from which a restricted low energy chemical mechanism is identified t