✦ LIBER ✦

Theoretical exploration of the water exchange mechanism of the polyoxocation GaO4Al12(OH)24(H2O)127+ in aqueous solution

✍ Scribed by Zhaosheng Qian; Hui Feng; Zhenjiang Zhang; Wenjing Yang; Miao Wang; Yingjie Wang; Shuping Bi

Book ID: 116503818
Publisher: Elsevier Science
Year: 2009
Tongue: English
Weight: 283 KB
Volume: 73
Category: Article
ISSN: 0016-7037
DOI: 10.1016/j.gca.2008.12.017

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Theoretical Investigation of Water Excha

Theoretical Investigation of Water Exchange on the Nanometer-Sized Polyoxocation AlO 4 Al 12 (OH) 24 (H 2 O) 127+ (Keggin-Al 13 ) in Aqueous Solution

✍ Qian, Zhaosheng; Feng, Hui; Yang, Wenjing; Bi, Shuping 📂 Article 📅 2008 🏛 American Chemical Society 🌐 English ⚖ 494 KB

Kinetics of oxygen exchange between site

Kinetics of oxygen exchange between sites in the GaO4Al12(OH)24(H2O)127+(aq) molecule and aqueous solution

✍ William H. Casey; Brian L. Phillips 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 438 KB

Activation volumes for oxygen exchange b

Activation volumes for oxygen exchange between the GaO4Al12(OH)24(H2O)127+(aq) (GaAl12) polyoxocation and aqueous solution from variable pressure 17O NMR spectroscopy

✍ John Loring; Ping Yu; Brian L Phillips; William H Casey 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Characterization of the galloaluminate G

Characterization of the galloaluminate GaO4Al12(OH)24(H2O)127+ polyoxocation by MAS NMR and infrared spectroscopies and powder x-ray diffraction

✍ Bradley, Susan M.; Kydd, Ronald A.; Fyfe, Colin A. 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 624 KB

Residence times for protons bound to thr

Residence times for protons bound to three oxygen sites in the AlO4Al12(OH)24(H2O)127+ polyoxocation

✍ Jacqueline R. Houston; Brian L. Phillips; William H. Casey 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 239 KB

Study of the hydrolysis of combined Al3+

Study of the hydrolysis of combined Al3+ and Ga3+ aqueous solutions: Formation of an extremely stable GaO4Al12(OH)24(H2O) polyoxycation

✍ Susan M. Bradley; Ronald A. Kydd; Raghav Yamdagni 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 429 KB

## Abstract ^71^Ga and ^27^Al NMR and clay mineral pillaring studies were used to investigate the hydrolysis of Al(H~2~O)–Ga(H~2~O) solutions, mixed in an Al:Ga mole ratio of 12:1, and confirmed the formation of the previously proposed GaO~4~Al~12~(OH)~24~(H~2~O) polyoxycation. This species has bee