Theoretical Estimation of the Activation Energy for the Reaction HO • + H 2 O → H 2 O + • OH: Importance of Tunneling
✍ Scribed by Hand, Michael R.; Rodriquez, Christopher F.; Williams, Ian H.; Balint-Kurti, Gabriel G.
- Book ID
- 126965824
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 107 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Since the activation energy for the reaction R H + 0 2 -+ R . + HO; is very close to its endothermicity, the R-H bond energy can be calculated from the activation energy for free radical formation by the reaction R H + 0 2 . The relation between Ei and QR-H was found empirically after measuring Ei b
## Abstract The flash photolysis resonance fluorescence technique has been used to measure the rate constant for the reaction equation image over the temperature range of 250–370 K. The present results are in excellent agreement with three very recent studies, and the combined data set can been u