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Theoretical Elucidation of Kinetic and Thermodynamic Control of Radical Addition Regioselectivity

✍ Scribed by Leach, Andrew G.; Wang, Renxiao; Wohlhieter, G. Erich; Khan, Saeed I.; Jung, Michael E.; Houk, K. N.

Book ID
126985137
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
230 KB
Volume
125
Category
Article
ISSN
0002-7863

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Sulfonation of meso-tetra(thien-2 0 -yl)porphyrin with concentrated sulfuric acid was found to produce several tetrasulfonated meso-tetra(thien-2 0 -yl)porphyrin isomers, where sulfonic acid groups were substituted at the 5-or the 4-positions of the thienyl groups, and the tetrasodium salts of the i