Potetitial energy curYe for the excited B "YE+ state of the Ily&o~en mdlxulc WBS computed for intemuc1cv distances u 1.2 -G R -z 5.0 nu.-l-he dissocirtion-crgescv~uatedforH\*,HD aryd D~~csbovctheexperimen~resultsby 0.9.3.1xnd 27.2 qn-', respectively. The wavefunctionsobtained are employed to conputc
Theoretical determination of vibration-rotation properties for the B1Σ+u state of H2
✍ Scribed by Sandra Z. Moody; Charles L. Beckel
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 358 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the paper, we compare the results of our ab initio calculations for the ro-vibrational branching ratios resultmg from a (3 + 1) REMPI of H, via the B 'X: state with the experimental data of Pratt, Poliakoff. Dehmer and Dehmer. These results indicate that non-Franck-Condon effects are less importa
Cross scct~ons fix vrbrntional c-xltntlon (VE) of the X 1 Z: state of LQ wa formation of the cxnted A '$ or B II-I" eiectromc states are reported. For VE through the A ' ~6 state. the cross secttons are nearly constant for forming X ' ?I; (3 < U" < 9) WI electron colhslonnl cwltatlon. For photon pum
The lowest order relativistic corrections to the electronic energies have been computed for the B 1E u state of H 2 in the interval 1.0 ~< R ~< 30 a 0. The total correction at the equilibrium separation, R = 2.43 a o amounts to -2.126 cm-1. The absolute shifts of the vibrational levels of H 2 change