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Theoretical determination of molecular structure. Conformation of some benzo[10]-annulenes and [10]-annulene

✍ Scribed by Jose Ma Hernando-Huelmo; Ma Jesús Rioseras-García

Publisher
Springer
Year
1993
Tongue
English
Weight
322 KB
Volume
87
Category
Article
ISSN
1432-2234

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✍ Shô Itô; Yoshimasa Fukazawa 📂 Article 📅 1974 🏛 Elsevier Science 🌐 French ⚖ 182 KB

In the previous paper (1) we have described a two-step synthesis of 1,6-methanaCl0lannulen-1 l-one from tropone. This compound, having the p-orbital of the carbonyl group .approximately perpendicular to the peripheral IOn-electron system, failed to exhibit appreciable n-n interaction between them. W