Theoretical derivation of solute-solvent interaction parameter in binary solution: Case of the deviation from Raoult's Law

Solute-solvent and solvent-solvent inter

Solute-solvent and solvent-solvent interactions in binary solvent mixtures. 2. Effect of temperature on the ET(30) polarity parameter of dipolar hydrogen bond acceptor-hydrogen bond donor mixtures

✍ Elisabeth Bosch; Martí Rosés; Koit Herodes; Ilmar Koppel; Ivo Leito; Ivar Koppel 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 560 KB

The effect of temperature on the Dimroth-Reichardt ET(30) parameter of binary mixtures of dimethyl sulfoxide, acetonitrile and nitromethane with alcohols and water was studied. The ET(30) polarity parameter of many of these binary mixtures exhibits a strong synergism. Dimethyl sulfoxide, acetonitril