Theoretical studies of spin-Hamiltonian
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Fang Wang; Wu Xiao-Xuan; Zheng Wen-Chen
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Article
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2008
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Elsevier Science
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English
⚖ 136 KB
In this paper, the high-order perturbation formulas of spin-Hamiltonian (SH) parameters (g factors g J , g ? and zero-field splitting D), including both the crystal-field (CF) and for the first time charge-transfer (CT) mechanisms, are established for 3d 8 ions in trigonal octahedral clusters. By us