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Theoretical calculations of glass transition temperatures of plasticized polymers

✍ Scribed by T. Czekaj; J. Kapko

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 188 KB
Volume: 17
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(81)90083-5

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✦ Synopsis

Based on free volume, an equation has been derived enabling calculation of glass transition temperature (To) of plasticized polymers, knowing the plasticizer content, the thermal expansion coefficients and values of To of the polymer and plasticizer. Determined and calculated TO are in satisfactory agreement up to the plasticizer concentration which dissolves the polymer.

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