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Theoretical calculation of rate constants and the mechanism of the elementary act in electron-exchange reactions between aromatic molecules and their radical anions

✍ Scribed by V. M. Berdnikov; G. A. Bogdanchikov; R. R. Dogonadze; T. M. Marsagishvili; A. M. Kuznetsov

Book ID: 112358379
Publisher: Springer
Year: 1982
Tongue: English
Weight: 603 KB
Volume: 17
Category: Article
ISSN: 0040-5760
DOI: 10.1007/bf00518132

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## Abstract The rate constant for the bimolecular combination of trichloromethyl radicals in methanol is determined as a function of temperature by steady‐state kinetics and electron‐spin resonance with modulated radical initiation. The rate constant is in accord with the Smoluchowski equation and