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Theoretical approach of the chemical reactivity: The SN2 reaction

✍ Scribed by Josiane Serre


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
754 KB
Volume
26
Category
Article
ISSN
0020-7608

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✦ Synopsis


Abstract

In this survey paper the different possible theoretical ways of treating the S~N~2 reaction are explained. It is shown that, in the future, experience and theory will very likely complement each other.


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## Abstract Ab initio calculations of negatively charged symmetrical and unsymmetrical transition states of the S~N~2β€² reaction indicate that due to electronic reasons and particularly Coulomb interactions the __anti__ transition state is generally more stable than the __syn__ transition state. The