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Theoretical analysis of vibronic coupling in the lowest T1[3A'2(ππ*)] state of triphenylene-h12 and-d12

✍ Scribed by Marek Z. Zgierski

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
258 KB
Volume
69
Category
Article
ISSN
0009-2614

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✦ Synopsis

The recently observed Tt -So evxtatton spectra of trtphenylene-lz 12 and -d,, are analysed m terms of Interstate pseudo-Jahn-Teller and mtrastate Jahn-Teller couplmg of the two lowest tnplrt states, T, [3A><nn*)] and T2[3E'(~*)], via an ~2' mode. Recently Nishi et al. [l] have reported a very interestmg experimental study of the tnplet state of tnphenylene by micro~vave-induced delayed phosphorescence and T + S exatation. The lowest two * issued as NRCC No 17930. * Research Assoctate.

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