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Theoretical Analysis of the Stereoselectivity in the Ozonolysis of Olefins. Evidence for a Modified Criegee Mechanism

✍ Scribed by Ponec, Robert; Yuzhakov, Gleb; Haas, Yehuda; Samuni, Uri

Book ID
121372813
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
174 KB
Volume
62
Category
Article
ISSN
0022-3263

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✍ Hiroyuki Saimoto; Catherine Houge; Anne-Marie Hesbain-Frisque; Anne Mockel; LΓ©on πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 226 KB

The stereospecificity of the olefin-keteneiminium salt reaction is shown to be dependent on the nitrogen substituents. This is taken as evidence for a stepwise mechanism.