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Theonellamide F Synthetic Studies. Stereoselective Synthesis of (3S, 4S, 5E, 7E)-3-Amino-8-(4-bromophenyl)-4-hydroxy-6-methyl-5,7-octadienoic acid (Aboa)

โœ Scribed by Keisuke Tohdo; Yasumasa Hamada; Takayuki Shioiri


Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
248 KB
Volume
33
Category
Article
ISSN
0040-4039

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Introduction. ~ Stereoselective C-C bond forming reactions catalyzed by chiral transition-metal complexes are a topic of fundamental importance [l]. In 1986, Hayashi and Zto reported an elegant asymmetric synthesis of dihydrooxazoles by an efficient gold(1)-catalyzed coupling of aldehydes with 2-iso