The ν1 bands of 32S18O2 and 34S18O2 from infrared-microwave double resonance
✍ Scribed by Josef Lindenmayer; Harold Jones; H.D. Rudolph
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 567 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
New measurements are reported for the infrared spectrum of sulfur trioxide, 32 S 16 O 3 , with resolutions ranging from 0.0015 cm -1 to 0.0025 cm -1 . Rovibrational constants have been measured for the fundamentals ν 2 , ν 3 , and ν 4 and the overtone band 2ν 3 . Comparisons are made with the earlie
Further analysis of the high-resolution (0.0015 cm -1 ) infrared spectrum of 32 S 16 O 3 has led to the assignment of more than 3100 hot band transitions from the ν 2 and ν 4 levels to the states 2ν 2 (l = 0), ν 2 + ν 4 (l = ±1), and 2ν 4 (l = 0, ±2). These levels are strongly coupled via Fermi reso