The Δk = ±2 and Δk = ±3 forbidden transitions in the vibrational-rotational spectra of symmetric top molecules NH3 and H3O+
✍ Scribed by D. Papoušek; Š. Urban; V. Špirko; K. Narahari Rao
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 326 KB
- Volume
- 141
- Category
- Article
- ISSN
- 0022-2860
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The IR-IR sub-Doppler double resonance and standard saturation sideband spectroscopy have been used to measure the allowed and Deltak = -3 forbidden transitions to the nu2 vibrational level of 14NH3. The IR-IR double resonance technique has made it possible to observe quadrupole hyperfine structures
The Fourier transform spectrum of the vibration-rotational bands \(v_{2}\) and \(v_{5}\) of gaseous fluoromethane \({ }^{13} \mathrm{CH}_{3} \mathrm{~F}\) was measured at an unapodized resolution \(0.0041 \mathrm{~cm}^{-1}\). Among the assigned lines, 102 belonged to the \(\Delta k= \pm 2\) perturba