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The X-ray photoelectron spectrum of a mixed valence compound of copper

โœ Scribed by Patrick Brant; Quintus Fernando

Book ID
115975102
Publisher
Elsevier Science
Year
1978
Weight
186 KB
Volume
40
Category
Article
ISSN
0022-1902

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X-ray photoelectron spectroscopy using copper( copper(I) and the mixed valence Cu(II)/Cu(i) compounds was empIoyed as a means of studying electron transfer reactions in copper proteins\_ The X-ray photoelectron spectra of copper(i1) compounds display characteristic satellites of both variable sire a

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and of reduced derivatives with 5, 12, and 24 electrons have been recorded. IV{40 signals are consistent with the presence of tetravalent tungsten in the reduced species. In particular the 12Fderivative does not contain WV but WIv and WV1 \_ m equal amounts. Valence band spectra show the W(Sd) level