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The X-ray crystal structure of the double-headed amphiphile (1S,2S)-1,2-bis(d-gluconamido)cyclohexane

✍ Scribed by Christoph André; Peter Luger; Daniel Nehmzow; Jürgen-Hinrich Fuhrhop

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
785 KB
Volume
261
Category
Article
ISSN
0008-6215

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✦ Synopsis

If a mixture of diastereomeric and enantiomeric 1,2-diaminocyclohexanes is amidated with o-glucono-l,Mactone, only one of the four diasteroeomeric amides, namely the title compound, crystallizes from the mixture. The same amide was also synthesized and crystallized from enantiomerically pure S,S-diamino-cyclohexane.

The lR,2R-diamide was also synthesized, but could not be crystallized. (lS,2S)-1,2-bis(o-gluconamidokyclohexane, C,$!,,N,O,,,

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